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Processing of a Novel Zn Alloy Micro-Tube for Biodegradable Vascular Stent Application

Wang Chang , Yu Zhentao , Cui Yajun , Zhang Yafeng , Yu Sen , Qu Gongqi , Gong Haibo

材料科学技术(英) doi:10.1016/j.jmst.2016.08.008

In recent years, zinc based alloys as a new biodegradable metal material aroused intensive interests. However, the processing of Zn alloys micro-tubes (named slender-diameter and thin-walled tubes) is very difficult due to their HCP crystal structure and unfavorable mechanical properties. This study aimed to develop a novel technique to produce micro-tube of Zn alloy with good performance for biodegradable vascular stent application. In the present work, a processing method that combined drilling, cold rolling and optimized drawing was proposed to produce the novel Zn-5Mg-1Fe (wt%) alloy micro-tubes. The micro-tube with outer diameter of 2.5?mm and thickness of 130?μm was fabricated by this method and its dimension errors are within 10?μm. The micro-tube exhibits a fine and homogeneous microstructure, and the ultimate tensile strength and ductility are more than 220?MPa and 20% respectively. In addition, the micro-tube and stents of Zn alloy exhibit superior in vitro corrosion and expansion performance. It could be concluded that the novel Zn alloy micro-tube fabricated by above method might be a promising candidate material for biodegradable stent.

关键词: Zn alloy , Micro-tube , Biodegradable stent , Mechanical properties , Dimensional accuracy , In vitro corrosion performance

Mathematic Model of SEN Clogging During Continuous Casting of Steel

WU Su-zhou , ZHANG Jiong-ming , LI ZHi-zheng

钢铁研究学报(英文版)

The SEN clogging is a long term issue for all the steelmakers. In the current study, the kinetics of SEN clogging during steel continuous casting was established. The dynamic build-up of alumina inclusions to the lining refractory of SEN was analyzed. The fluid flow and inclusions motion are calculated by means of mathematic model. Effect of diameters of inclusions, roughness of nozzle, diameter of nozzle and casting speed on the entrapment probability are estimated.

关键词: nozzle clogging;mathematic model;inclusion motion

薄板坯连铸用SEN的开发和渣线材料抗侵蚀性能浅谈

李红霞 , 杨彬 , 杨金松 , 刘国齐 , 刘红康

连铸 doi:10.3969/j.issn.1005-4006.2003.02.012

对薄板坯连铸用浸入式水口(SEN)进行一些技术改进,如在SEN表面使用高抗氧化性能涂料,在ZrO2-C渣线的材料中加入复合防氧化添加剂以及采用高质量的熔融氧化锆材质等,使新型SEN显示出良好的抗热震性和抗侵蚀性.对使用后的SEN微观结构进行分析,渣线被侵蚀的主要原因是液态渣与ZrO2中的稳定剂CaO的反应和石墨被钢液氧化.

关键词:

INFLUENCES OF CASTING SPEED AND SEN DEPTH ON FLUID FLOW IN THE FUNNEL TYPE MOLD OF A THIN SLAB CASTER

B.W. Li , X.Y. Tian , E.G. Wang , J.C. He , null , null , null , null

金属学报(英文版)

In recent years, thin slab continuous casting technology has been widely used to improve the quality of the product and to reduce the cost. One of the challenges faced by this technology is to design reasonable flow patterns, which strongly affect the surface and inner properties of the final slab in the mold. With the fixed scales and complex geometrical structures of nozzle and funnel type mold, a series of numerical simulations are made to analyze the flow patterns in melt steel using finite volume method based on structured body fitted coordinate grids. The CFD (computational fluid dynamics) package is validated first using one typical case described in previously published studies, and then it is developed to study the effect of operational parameters on fluid flow in thin slab caster. Two operational parameters, casting speed and SEN depth (submerged entry nozzle), are mainly considered for numerical analysis. On the basis of present simulations, the reasonable SEN submergence depths corresponding to different casting speeds are suggested according to fluid flow characteristics like, flow jet impingement on the narrow side of the mold, flow speed of the melt steel beneath the meniscus and the recirculation region. This is the first stage of study on the numerical analysis of the whole thin slab casting process with electromagnetic brake.

关键词: continuous casting , null , null

SEN底部形状对结晶器内钢液流场和温度场的影响

王翠娜 温良英 陈登福 张大江 彭政 靳星

钢铁

针对某钢厂板坯连铸结晶器及浸入式水口(SEN)的结构参数,建立了描述结晶器内钢液流动的三维数学模型,用FLUENT软件对结晶器内钢液的流场和温度场进行耦合计算,分析SEN底部形状对结晶器内流场和温度场的影响。结果表明:凸底水口出口附近钢液的速度较大,对结晶器窄面的冲击深度较大,使结晶器内高温区下移,不利于凝固坯壳的生长;平底水口自由面速度较大、温度较高,有利于保护渣的熔化,但易产生液面裸露现象;凹底自由面速度较小、温度较低,有利于液面稳定。

关键词: 浸入式水口(SEN);底部形状;结晶器;流场;温度场

SEN底部形状对结晶器内钢液流场和温度场的影响

王翠娜 , 温良英 , 陈登福 , 张大江 , 彭政 , 靳星

钢铁

针对某钢厂板坯连铸结晶器及浸入式水口(SEN)的结构参数,建立了描述结晶器内钢液流动的三维数学模型,应用FLUENT软件对结晶器内钢液的流场和温度场进行耦合计算,分析SEN底部形状对结晶器内流场和温度场的影响,并利用水模试验对钢液的流动行为进行了验证.结果表明:凸底水口出口附近钢液的速度较大,流股的冲击深度较大,使结晶器内高温区下移,不利于凝固坯壳的生长;平底水口自由面速度较大、温度较高,有利于保护渣的熔化,但易产生液面裸露现象;凹底自由面速度较小、温度较低,有利于液面稳定.

关键词: 浸入式水口 , 底部形状 , 结晶器 , 流场 , 温度场

EFFECT OF SUBMERGED ENTRY NOZZLE (SEN) PARAMETERS AND SHAPE ON 3-D FLUID FLOW IN MOULD FOR BEAM BLANK CONTINUOUS CASTING

Y.P.Du

金属学报(英文版)

According to turbulent theory and characteristics of beam blank continuous casting, 3-D model to represent the flow of beam blank mould is established. The predicted results indicate that the exit obliquity of up 15°(+15°) should be adopted, which will benefit the floatation of non-metallic inclusion and purification of the molten steel. When the nozzle angle is 120°, the flow pattern is reasonable. Proper nozzle depth can be 200ram. Turbulent kinetic of meniscus can be reduced by adopting the square nozzle and suitable area of side outlet when casting speed increases. The results are consistent with those of water model experiment, so the model is exact and reasonable. The model can provide important information for design of SEN and defining of immersion depth.

关键词: SEN parameter , null , null

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